Borane as an efficient directing group. Stereoselective 1,2-addition of organometallic reagents to borane P-stereogenic N-phosphanylimines

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Título:	Borane as an efficient directing group. Stereoselective 1,2-addition of organometallic reagents to borane P-stereogenic N-phosphanylimines
Autor/a:	Flores-Gaspar, Areli; Orgué Gassol, Sílvia; Grabulosa, Arnald; Riera i Escalé, Antoni; Verdaguer i Espaulella, Xavier
Otros autores:	Universitat de Barcelona
Abstract:	In non-coordinating solvents, borane was shown to be an efficient directing group for the stereoselective 1,2-addition of organolithium reagents to P-stereogenic N-phosphanylimines. Selectivity was reversed in coordinating solvents. This process can lead to novel ligand scaffolds for asymmetric catalysis.
Materia(s):	-Compostos organometàl·lics -Lligands (Bioquímica) -Catàlisi asimètrica -Organometallic compounds -Ligands (Biochemistry) -Enantioselective catalysis
Derechos:	(c) Flores-Gaspar, Areli et al., 2014
Tipo de documento:	Artículo Artículo - Versión aceptada
Editor:	Royal Society of Chemistry
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Orgué Gassol, Sílvia; Flores-Gaspar, Areli; Biosca, Maria; Pàmies, Oscar; Diéguez, Montserrat; Riera i Escalé, Antoni; Verdaguer i Espaulella, Xavier

Orgué Gassol, Sílvia; Flores-Gaspar, Areli; Biosca, Maria; Pàmies, Oscar; Diéguez, Montserrat; Riera i Escalé, Antoni; Verdaguer i Espaulella, Xavier

Salomó, Ernest; Orgué Gassol, Sílvia; Riera i Escalé, Antoni; Verdaguer i Espaulella, Xavier

Salomó, Ernest; Orgué Gassol, Sílvia; Riera i Escalé, Antoni; Verdaguer i Espaulella, Xavier

Orgué Gassol, Sílvia; Leon, Thierry; Riera i Escalé, Antoni; Verdaguer i Espaulella, Xavier

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