Title:
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Effects of thickness on the cation segregation in epitaxial (001) and (110) La2/3Ca1/3MnO3 thin films
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Author:
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Estradé Albiol, Sònia; Rebled, J. M. (José Manuel); Arbiol i Cobos, Jordi; Peiró Martínez, Francisca; Infante, I. C.; Herranz, G.; Sánchez, F.; Fontcuberta i Griñó, Josep; Córdoba, R.; Mendis, B. G.; Bleloch, A. L.
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Other authors:
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Universitat de Barcelona |
Abstract:
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Electron-energy-loss spectroscopy is used to map composition and electronic states in epitaxial La2/3Ca1/3MnO3 LCMO films of various thicknesses grown on SrTiO3 001 and 110 substrates. For relatively thick films 20 nm , epitaxial tensile strain in 001 films promotes a compositional La/Ca gradient across the film thickness, being the interface La rich, while the relaxed 110 films are chemically homogeneous. In contrast, much thinner 001 and 110 LCMO films display a different La/Ca distribution, being La rich at the free surface. The observed distinct thickness-dependent composition gradient behavior reflects a balance between strain-induced elastic energy minimization and kinetic effects during growth. |
Subject(s):
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-Cations -Pel·lícules fines -Espintrònica -Espectroscòpia de pèrdua d'energia d'electrons -Cations -Thin films -Spintronics -Electron energy loss spectroscopy |
Rights:
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(c) American Institute of Physics , 2009
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Document type:
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Article Article - Published version |
Published by:
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American Institute of Physics
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